The importance of a conjoint action of corrosion and stress as well as the nature of. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby. It is caused by a combination of material properties now recognized as affecting mostly high strength alloys, it occurs in part under high tensile strength and the grain structure of the material. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. On the mechanism of intergranular corrosion of aluminum alloys. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain. Intergranular oxidation igo intergranular attack iga. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Intergranular attack in welded stresscorrosion resistant. Grain boundary selective oxidation and intergranular.
Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. Intergranular stress corrosion cracking of copper a case study. Temperature is a significant environmental factor affecting cracking. Mechanistic aspects of intergranular stress corrosion. Observations of corrosion product formation and stress.
The stress corrosion cracking scc of aluminum alloys is a welldocumented phenomenon, but there is considerable disagreement in the scientific literature as to what mechanism causes it. The postulated mechanisms for stress corrosion cracking of. A mechanism for hydrogeninduced intergranular stress. The mechanism of intergranular corrosion was summarized by sinyavskii et al. Recognize the mechanism for igscc and the conditions that make igscc more likely.
The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Intergranular corrosion is localized attack along the grain boundaries, or immediately adjacent to grain boundaries, while the bulk of the grains remain largely unaffected. Stress corrosion cracking scc stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Intergranular corrosion mechanism of slightlysensitized. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress.
Cracking of sensitized stainless steels inspectioneering. Evidence of intergranular attack iga in the absence of stress, together with dissolution kinetics, indicates that intergranular stress corrosion cracking igscc of ferritic steels in various environments is by a dissolution mechanism. Intergranular stress corrosion cracking igscc of alloy 600 in hightemperature, deaerated water or steam has been termed hydrogeninduced igscc. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Stress corrosion cracking an overview sciencedirect topics. Intergranular corrosion causes the reduction in grain size. Intergranular attack in welded stresscorrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. This type of failure is known as stress corrosion cracking, often abbreviated to scc. The incidence of intergranular stress corrosion cracking within the heataffected zone is closely linked to the depletion of chromium content of adjoining grain boundaries. Stress corrosion cracking scc near the fusion boundary of a 316ng stainless steel ss welded joint in hightemperature water was investigated with emphasis on the relation to the.
Figure 43 an example of intergranular cracking of pipeline steel revie 2000. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Stresscorrosion cracking is a timedependent, predominantly intergranular fracture mode in aluminum alloys that requires the simultaneous presence of a susceptible alloy, a sustained tensile stress and a corrosive environment. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The role of local strains from prior cold work on stress corrosion cracking of. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. The grain boundaries are anodically attacked in presence of an electrolyte. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. This form of corrosion is usually associated with chemical segregation effects impurities have a tendency to be enriched at grain boundaries or specific phases. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to protect the structure 71.
Sensitization, intergranular attack, stress corrosion. Intergranular stress corrosion cracking of welded steel twi. Aluminium based alloys may be sensitive to intergranular corrosion if there are layers of materials acting as anodes between the aluminiumrich crystals. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. High strength aluminium alloys, especially when extruded or otherwise subjected to high degree of working, can undergo exfoliation corrosion metallurgy. In this chapter, the conditions for the occurrence of scc are first introduced. Occasionally, both types of cracking are observed in a failure. Modelling intergranular stress corrosion cracking in. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full.
Stress corrosion cracking may be defined as cracking owing to a process involving conjoint corrosion and straining of a metal because of residual or applied stress. The stresses required are tensile and essentially static. Though it is easy to identify intergranular cracking, pinpointing the cause is more complex as the mechanisms are more varied, compared to transgranular fracture. This causes depletion of chromium from the austenitic grains resulting in decreasing the corrosion protective passive film. The photos above show the microstructure of a type 304 stainless steel. During heat treatment certain conditions can cause a material to become susceptible to intergranular attack a. The presence of flaws that concentrate stress or crevices that alter. The scc susceptibility of these materials under mixed. This paper deals with intergranular stress corrosion cracking igscc mechanisms in nibase alloys in various corrosive environments such as deaerated water, airsaturated chloride medium, and caustic solutions at high temperatures with focus on cr content and cr carbide precipitation at grain boundaries in the alloys. Stress corrosion cracking is a progressive type of failure that causes cracks at stress levels well below a materials yield point. It has been reported that at times, even in very weak solutions, sensitization may induce intergranular corrosion attack. Gooch introduction although austenitic stainless steels. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. These alloys can be sensitized during operation, promoting their susceptibility to intergranular stress corrosion cracking igscc.
Intergranular fracture an overview sciencedirect topics. It is, therefore, important that the phenomenon is. Stresscorrosion cracking in aluminum alloys is characteristically intergranular. Intergranular stress corrosion cracking igscc is more common than transgranular scc. The interaction of corrosion fatigue and stresscorrosion. This work examines the effect of sensitization on the stress corrosion cracking behavior of marine grade aluminum alloys almg. Setup and results of a grain scale model of intergranular cracking. Stress corrosion cracking can proceed in one of two ways. This work focused on the intergranular corrosion mechanism of. Transgranular stress corrosion cracking of highpressure. Introduction the mechanism of transgranular stress corrosion cracking tgscc. Intergranular stress corrosion cracking igscc is a mode of subcritical crack propagation in susceptible nickelbased alloys and austenitic stainless steels used in power generation.
What is intergranular stress corrosion cracking igscc. Intergranular cracks follow the grain boundaries in the metal. A number of research works have been conducted for clarification of the mechanism of intergranular stress corrosion cracking igscc in girth welds of high grade supermartensitic stainless steel smss. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Exposure to certain unsuitable combinations of time at elevated temperature either during the fabrication of the sheet and plate products or in. Highpurity copper is immune to stress corrosion cracking in most.
However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. Film rupture can play an important role in the rate of growth of cracks. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. We believe these cracks are initiated by the nucleation of a high density of bubbles on the grain. Intergranular stress corrosion cracking an overview. Environmental cracking results from the conjoint action of three components. There are several other processes that can lead to intergranular fracture, or preferential crack propagation at the grain boundaries. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to. An intergranular attack is caused by the segregation of impurities at the grain boundaries or by enrichment or depletion of one of the alloying elements in the grain boundary areas. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. Intergranular corrosion is a typical defect of austenitic and nickel alloys.
Stress corrosion cracking international institute of. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled by methods such as the lowering of carbon content, solution heat treatment. Interpretation of the behavior of carbide prcipitation in. Intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. They are usually below the macroscopic yield stress but sufficient to induce. Mod01 lec27 pitting corrosion, intergranular corrosion. Kallol mondal,department of metallurgy and material science,iit kanpur. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline.